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High-Efficiency Polymer:Nonfullerene Solar Cells with Quaterthiophene-Containing Polyimide Interlayers.


ABSTRACT: Interfacial layers (interlayers) are one of the emerging approaches in organic solar cells with bulk heterojunction (BHJ) layers because the solar cell efficiency can be additionally improved by their presence. However, less attention is paid to the use of interlayers for polymer:nonfullerene solar cells, which have strong advantages over polymer:fullerene solar cells. In addition, most polymers used for the interlayers possess a low glass transition temperature (Tg). Here, it is demonstrated that two types of quarterthiophene-containing polyimides (PIs) with high Tg (>198 °C), which are synthesized using pyromellitic dianhydride (PMDA) and cyclobutane-1,2,3,4-tetracarboxylic dianhydride (CTCDA), can act as an interfacial layer in the polymer:nonfulleren

SUBMITTER: Park E 

PROVIDER: S-EPMC6097094 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature