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Enantiomer-specific measurements of current-use pesticides in aquatic systems.


ABSTRACT: Some current-use pesticides are chiral and have nonsuperimposable mirror images called enantiomers that exhibit identical physical-chemical properties but can behave differently when in contact with other chiral molecules (e.g., regarding degradation and uptake). These differences can result in variations in enantiomer presence in the environment and potentially change the toxicity of pesticide residues. Several current-use chiral pesticides are applied in urban and agricultural areas, with increased potential to enter watersheds and adversely affect aquatic organisms. The present study describes a stereoselective analytical method for the current-use pesticides fipronil, cis-bifenthrin, cis-permethrin, cypermethrin, and cyfluthrin. We show use of the method by characterizing enantiomer fr

SUBMITTER: Ulrich EM 

PROVIDER: S-EPMC6098700 | biostudies-literature | 2018 Jan

REPOSITORIES: biostudies-literature