Heterometallic ZnII⁻LnIII⁻ZnII Schiff Base Complexes with Linear or Bent Conformation-Synthesis, Crystal Structures, Luminescent and Magnetic Characterization.

ABSTRACT: A series of racemic, heteronuclear complexes [Zn₂Nd(ac)₂(HL)₂]NO₃·3H₂O (1), [Zn₂Sm(ac)₂(HL)₂]NO₃·3CH₃OH·0.3H₂O (2), [Zn₂Ln(ac)₂(HL)₂]NO₃·5.33H₂O (3⁻5) (where HL is the dideprotonated form of N,N'-bis(5-bromo-3-methoxysalicylidene)-1,3-diamino-2-propanol, ac = acetate ion, and Ln = Eu (3), Tb (4), Dy (5), respectively) with an achiral multisite coordination Schiff base ligand (H₃L) were synthesized and characterized. The X-ray crystallography revealed that the chirality in complexes is centered at lanthanide(III) ions due to two vicinally located μ-acetato-bridging ligands. The presented crystals have isoskeletal coordination units but they crystallize in monoclinic (1, 2) or trigonal crystal systems (3⁻5) with slightly different conformation. In 1 and 2 the ZnII⁻LnIII⁻ZnII coordination cor

SUBMITTER: Miroslaw B 

PROVIDER: S-EPMC6099393 | biostudies-literature | 2018 Jul

REPOSITORIES: biostudies-literature