Nickel Sulfides Decorated SiC Foam for the Low Temperature Conversion of H₂S into Elemental Sulfur.

ABSTRACT: The selective oxidation of H₂S to elemental sulfur was carried out on a NiS₂/SiCfoam catalyst under reaction temperatures between 40 and 80 °C using highly H₂S enriched effluents (from 0.5 to 1 vol.%). The amphiphilic properties of SiC foam provide an ideal support for the anchoring and growth of a NiS₂ active phase. The NiS₂/SiC composite was employed for the desulfurization of highly H₂S-rich effluents under discontinuous mode with almost complete H₂S conversion (nearly 100% for 0.5 and 1 vol.% of H₂S) and sulfur selectivity (from 99.6 to 96.0% at 40 and 80 °C, respectively), together with an unprecedented sulfur-storage capacity. Solid sulfur was produced in large aggregates at the outer catalyst surface and relatively high H₂S conversion was maintained until sulfur deposits reached 140

SUBMITTER: Duong-Viet C 

PROVIDER: S-EPMC6099843 | biostudies-literature | 2018 Jun

REPOSITORIES: biostudies-literature