Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

PDMS-coated hypercrosslinked porous organic polymers modified via double postsynthetic acidifications for ammonia capture.

ABSTRACT: A hypercrosslinked porous organic polymer was modified by post-oxidation and post-sulfonation to obtain a porous platform with a high density of acidic groups. Such an acidified material exhibits record high NH₃ adsorption capacity per surface area, fast adsorption rate, and recyclability at low desorption temperature. Noticeably, the coating of the polymer with PDMS represents a facile and efficient route to enable both a significant improvement of low-pressure NH₃ adsorption capacity (∼40-fold enhancement; from 0.04 to 1.41 mmol g^-1) with respect to the non-modified polymer at 500 ppm and hydrophobicity associated with the selective sorption of NH₃ over water vapor (hydrophilic for the non-coated material). This material is easy to prepare, cost-effective, and scalable to mass production.

SUBMITTER: Kang DW

PROVIDER: S-EPMC6114995 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

PDMS-coated hypercrosslinked porous organic polymers modified via double postsynthetic acidifications for ammonia capture.

Kang Dong Won DW Kang Minjung M Moon Minkyu M Kim Hyojin H Eom Sunhwi S Choe Jong Hyeak JH Lee Woo Ram WR Hong Chang Seop CS

Chemical science 20180718 33

A hypercrosslinked porous organic polymer was modified by post-oxidation and post-sulfonation to obtain a porous platform with a high density of acidic groups. Such an acidified material exhibits record high NH3 adsorption capacity per surface area, fast adsorption rate, and recyclability at low desorption temperature. Noticeably, the coating of the polymer with PDMS represents a facile and efficient route to enable both a significant improvement of low-pressure NH3 adsorpt ...[more]

PMID: 30310620

Similar Datasets

Multifunctional Hypercrosslinked Porous Organic Polymers Based on Tetraphenylethene and Triphenylamine Derivatives for High-Performance Dye Adsorption and Supercapacitor.

Project description:We successfully prepared two different classes of hypercrosslinked porous organic polymers (HPPs)-the tetraphenylethene (TPE) and (4-(5,6-Diphenyl-1H-Benzimidazol-2-yl)-triphenylamine (DPT) HPPs-through the Friedel-Crafts polymerization of tetraphenylethene and 4-(5,6-diphenyl-1H-benzimidazol-2-yl)-triphenylamine, respectively, with 1,4-bis(chloromethyl)benzene (Ph-2Cl) in the presence of anhydrous FeCl3 as a catalyst. Our porous materials exhibited high BET surface areas (up to 1000 m2 g-1) and good thermal stabilities. According to electrochemical and dyes adsorption applications, the as-prepared DPT-HPP exhibited a high specific capacitance of 110 F g-1 at a current density of 0.5 A g-1, with an excellent cycling stability of over 2000 times at 10 A g-1. In addition, DPT-HPP showed a high adsorption capacity up to 256.40 mg g-1 for the removal of RhB dye from water.

| S-EPMC7589367 | biostudies-literature

Hypercrosslinked porous polymers hybridized with graphene oxide for water treatment: dye adsorption and degradation.

Project description:Hypercrosslinked porous polymer hybridized graphene oxide with polymeric high internal phase emulsions (polyHIPEs/GO) were designed as versatile composites for water treatment. Morphologies, chemical composition and thermal stability of the composites were characterized by SEM, FTIR, XPS, XRD and TGA. Tunable adsorption properties and enhanced visible-light photocatalysis towards organic dyes were achieved by the manipulation of functional groups and the inclusion of Ag3PO4, respectively. The adsorption capacity of polyHIPEs/GO towards cationic methyl blue (MB) and rhodamine B (RB) is 1250.3 and 1054.1 μg g-1, respectively. Aminated polyHIPEs/GO (polyHIPEs(NH2)/GO) possesses an adsorption capacity of 1967.3 μg g-1 to anionic eosin Y (EY). The tandem columns of polyHIPEs(NH2)/GO and polyHIPEs/GO can successively and selectively remove the cationic and anionic dyes in a mixed dye solution. Furthermore, enhanced photodegradation ability was obtained after GO reduction and Ag3PO4 addition on polyHIPEs(NH2)/GO. Results show that 3.5 × 10-5 M of MB, RB and EY can be completely photodegraded by 20 mg of the novel photocatalyst within 20, 40 and 35 min, respectively. This work demonstrates that polyHIPEs/GO exhibits tunable properties for multiply progressive applications in water treatment and catalysis.

| S-EPMC9079756 | biostudies-literature

Azo-Linked Porous Organic Polymers for Selective Carbon Dioxide Capture and Metal Ion Removal.

Project description:The facile and environmentally friendly synthesis of porous organic polymers with designed polar functionalities decorating the interior frameworks as an excellent adsorbent for selective carbon dioxide capture and metal ion removal is a target worth pursuing for environmental applications. In this regard, two azo-linked porous organic polymers denoted man-Azo-P1 and man-Azo-P2 were synthesized in water by the azo-linking of 4,4'-diaminobiphenyl (benzidine) and 4,4'-methylenedianiline, respectively, with 1,3,5-trihydroxybenzene. The resulting polymers showed good BET surface areas of 290 and 78 m2 g-1 for man-Azo-P1 and man-Azo-P2, respectively. Due to the enriched core functionality of the azo (-N=N-) and hydroxyl groups along with the porous frameworks, man-Azo-P1 exhibited a good CO2 uptake capacity of 32 cm3 g-1 at 273 K and 1 bar, in addition to the remarkable removal of lead (Pd), chromium (Cr), arsenic (As), nickel (Ni), copper (Cu), and mercury (Hg) ions. This performance of the synthesized man-Azo-P1 and man-Azo-P2 in the dual application of CO2 capture and heavy metal ion removal highlights the unique properties of azo-linked POPs as excellent and stable sorbent materials for the current challenging environmental applications.

| S-EPMC9088788 | biostudies-literature

Synthesis of Electron-Rich Porous Organic Polymers via Schiff-Base Chemistry for Efficient Iodine Capture.

Project description:As one of the main nuclear wastes generated in the process of nuclear fission, radioactive iodine has attracted worldwide attention due to its harm to public safety and environmental pollution. Therefore, it is of crucial importance to develop materials that can rapidly and efficiently capture radioactive iodine. Herein, we report the construction of three electron-rich porous organic polymers (POPs), denoted as POP-E, POP-T and POP-P via Schiff base polycondensations reactions between Td-symmetric adamantane knot and four-branched "linkage" molecules. We demonstrated that all the three POPs showed high iodine adsorption capability, among which the adsorption capacity of POP-T for iodine vapor reached up to 3.94 g·g-1 and the removal rate of iodine in n-hexane solution was up to 99%. The efficient iodine capture mechanism of the POP-T was investigated through systematic comparison of Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS) before and after iodine adsorption. The unique π-π conjugated system between imine bonds linked aromatic rings with iodine result in charge-transfer complexes, which explains the exceptional iodine capture capacity. Additionally, the introduction of heteroatoms into the framework would also enhance the iodine adsorption capability of POPs. Good retention behavior and recycling capacity were also observed for the POPs.

| S-EPMC9415008 | biostudies-literature

Triazine-based porous organic polymers for reversible capture of iodine and utilization in antibacterial application.

Project description:The capture and safe storage of radioactive iodine (129I or 131I) are of a compelling significance in the generation of nuclear energy and waste storage. Because of their physiochemical properties, Porous Organic Polymers (POPs) are considered to be one of the most sought classes of materials for iodine capture and storage. Herein, we report on the preparation and characterization of two triazine-based, nitrogen-rich, porous organic polymers, NRPOP-1 (SABET = 519 m2 g-1) and NRPOP-2 (SABET = 456 m2 g-1), by reacting 1,3,5-triazine-2,4,6-triamine or 1,4-bis-(2,4-diamino-1,3,5-triazine)-benzene with thieno[2,3-b]thiophene-2,5-dicarboxaldehyde, respectively, and their use in the capture of volatile iodine. NRPOP-1 and NRPOP-2 showed a high adsorption capacity of iodine vapor with an uptake of up to 317 wt % at 80 °C and 1 bar and adequate recyclability. The NRPOPs were also capable of removing up to 87% of iodine from 300 mg L-1 iodine-cyclohexane solution. Furthermore, the iodine-loaded polymers, I2@NRPOP-1 and I2@NRPOP-2, displayed good antibacterial activity against Micrococcus luteus (ML), Escherichia coli (EC), and Pseudomonas aeruginosa (PSA). The synergic functionality of these novel polymers makes them promising materials to the environment and public health.

| S-EPMC8850422 | biostudies-literature

Synthesis of Porous Organic Polymers with Tunable Amine Loadings for CO2 Capture: Balanced Physisorption and Chemisorption.

Project description:The cross-coupling reaction of 1,3,5-triethynylbenzene with terephthaloyl chloride gives a novel ynone-linked porous organic polymer. Tethering alkyl amine species on the polymer induces chemisorption of CO2 as revealed by the studies of ex situ infrared spectroscopy. By tuning the amine loading content on the polymer, relatively high CO2 adsorption capacities, high CO2-over-N2 selectivity, and moderate isosteric heat (Qst) of adsorption of CO2 can be achieved. Such amine-modified polymers with balanced physisorption and chemisorption of CO2 are ideal sorbents for post-combustion capture of CO2 offering both high separation and high energy efficiencies.

| S-EPMC6669882 | biostudies-literature

Highly efficient, reversible iodine capture and exceptional uptake of amines in viologen-based porous organic polymers.

Project description:A viologen-based porous organic polymer, POP-V-VI, was designed and synthesized by a facile nucleophilic substitution between cyanuric chloride and 1,2-bis(4-pyridinium) ethylene. Together with the reported POP-V-BPY with a similar structure, these viologen-based porous organic polymers bear high charge density, phenyl ring and nitrogenous affinity sites, which endow them with excellent iodine vapor uptake capacity (4860 mg g-1 for POP-V-VI and 4200 mg g-1 for POP-V-BPY) and remarkably high adsorption capacity for pyridine (4470 mg g-1 for POP-V-VI and 8880 mg g-1 for POP-V-BPY) and other aliphatic amines. POP-V-VI and POP-V-BPY could be efficiently recycled and reused three times without significant loss of iodine vapor uptake. All these results demonstrate that POP-V-VI and POP-V-BPY are promising adsorbents for practical applications in portable devices such as gas masks.

| S-EPMC9054242 | biostudies-literature

Porous inorganic-organic shape memory polymers.

Project description:Thermoresponsive shape memory polymers (SMPs) are a type of stimuli-sensitive materials that switch from a temporary shape back to their permanent shape upon exposure to heat. While the majority of SMPs have been fabricated in the solid form, porous SMP foams exhibit distinct properties and are better suited for certain applications, including some in the biomedical field. Like solid SMPs, SMP foams have been restricted to a limited group of organic polymer systems. In this study, we prepared inorganic-organic SMP foams based on the photochemical cure of a macromer comprised of inorganic polydimethylsiloxane (PDMS) segments and organic poly(?-caprolactone) (PCL) segments, diacrylated PCL(40)-block-PDMS(37)-block-PCL(40). To achieve tunable pore size with high interconnectivity, the SMP foams were prepared via a refined solvent-casting/particulate-leaching (SCPL) method. By varying design parameters such as degree of salt fusion, macromer concentration in the solvent and salt particle size, the SMP foams with excellent shape memory behavior and tunable pore size, pore morphology, and modulus were obtained.

| S-EPMC3433079 | biostudies-literature

Conversion of CO2 into Chloropropene Carbonate Catalyzed by Iron (II) Phthalocyanine Hypercrosslinked Porous Organic Polymer.

Project description:Commercial iron (II) phthalocyanine (FePc) was knitted with biphenyl using a Friedel-Crafts reaction to yield a micro-meso porous organic polymer (FePc-POP) with a specific surface area of 427 m2/g and 5.42% of iron loading. This strategy allowed for the direct synthesis of a heterogeneous catalyst from an iron containing monomer. The catalytic system, formed by the knitted polymer containing FePc and DMAP (4-dimethylamino pyridine) as base, results in an efficient heterogeneous catalyst in the cycloaddition of CO2 to epichlorohydrin to selectively obtain the corresponding cyclic carbonate. Thus, a TON (mmol substrate converted/mmol catalysts used) value of 2700 was reached in 3 h under mild reaction conditions (solvent free, 90 °C, 3 bar of CO2). The catalyst does not exhibit leaching during the reactions, which was attributed to the excellent stability of the metal in the macrocycle.

| S-EPMC7587207 | biostudies-literature

Superhydrophobic Coating Based on Porous Aluminum Oxide Modified by Polydimethylsiloxane (PDMS).

Project description:The aim of this study was to obtain a superhydrophobic coating by modifying anodized aluminum using polydimethylsiloxane (PDMS). In order to obtain a superhydrophobic coating on an aluminum substrate, a multistage treatment was implemented. Specimens of aluminum were treated by abrasive blasting, anodization in sulfuric acid, impregnation by PDMS, rinsing in toluene to remove excess of PDMS, and curing. A rough surface with an additional low free energy layer on it resulted in a superhydrophobic effect. The coating obtained has an average contact angle of 159°. The specimens were tested in terms of durability in natural conditions. Additionally, anti-icing and anti-fouling properties were evaluated. The coating was compared with anodized aluminum obtained by a basic process.

| S-EPMC8840686 | biostudies-literature