Synthesis and structural characterization of inverse-coordination clusters from a two-electron superatomic copper nanocluster.

ABSTRACT: We have synthesized and structurally characterized a series of centred cuboctahedral copper clusters, namely [Cu₁₃{S₂CNR₂}₆{C[triple bond, length as m-dash]CR'}₄](PF₆), 1a-d (where a: R = ⁿ Bu, R' = CO₂Me; b: R = ⁿ Bu, R' = CO₂Et; c: R = ⁱPr, R' = CO₂Et; d: R = ⁿ Pr, R' = 3,5-(CF₃)₂C₆H₃); [Cu₁₂(μ₁₂-S){S₂CNR₂}₆{C[triple bond, length as m-dash]CR'}₄], 2a-c; [Cu₁₂(μ₁₂-Cl){S₂CNR₂}₆{C[triple bond, length as m-dash]CR'}₄

SUBMITTER: Chakrahari KK 

PROVIDER: S-EPMC6115619 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature