Hypercoordinated Oligosilanes Based on Aminotrisphenols.

ABSTRACT: The hypercoordinated silicon chlorides ClSi[(o-OC₆H₄)₃N] (3) and ClSi[(OC₆H₂Me₂CH₂)₃N] (5) were used for the synthesis of catenated derivatives (Me₃Si)₃SiSi[(o-OC₆H₄)₃N] (9), (Me₃Si)₃SiSiMe₂SiMe₂Si(SiMe₃)₂Si[(o-OC₆H₄)₃N] (11), and (Me₃Si)₃SiSi[(OC₆H₂Me₂CH₂)₃N] (13) in reactions with (Me₃Si)₃SiK·THF (7) or (Me₃Si)₃SiK·[18-crown-6] (8). It was found that the nature o

SUBMITTER: Aghazadeh Meshgi M 

PROVIDER: S-EPMC6120741 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature