Crystal structure and Hirshfeld surface analysis of methyl 4-[(E)-2-(5-bromo-2-meth-oxy-benzyl-idene)hydrazin-yl]-3-nitro-benzoate.

ABSTRACT: The title compound, C₁₆H₁₄BrN₃O₅, is a novel halogen (Br) substituted hydrazine derivative. The hydrazine derivatives were the group of compounds with the general structure, R₁R₂C=NNH₂ (Uppal et al., 2011 ▸), with the central RC=NNH₂ moiety bridging two different groups on both sides. An all-trans configuration of the backbone (RC=NNH₂) results in an extended mol-ecular conformation. The dihedral angle between the 5-bromo-2-meth-oxy-phenyl ring and the nitrophenyl ring is 4.4 (3)°. Intra-molecular N-H⋯O inter-actions form S(6) graph-set motifs, while C-H⋯O and C-H⋯N inter-actions form S(5) graph-set motifs. Symmetry-related mol-ecules ar

SUBMITTER: Malek TJ 

PROVIDER: S-EPMC6127684 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature