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Crystal structure and luminescent properties of bis-[2,6-dimethyl-3-(pyridin-2-yl-κN)pyridin-4-yl-κC⁴](2,2,6,6-tetra-methylhepta-ne-3,5-dionato-κ²O,O')iridium(III) ethyl acetate monosolvate.

ABSTRACT: In the solvated title compound, [Ir(C₁₂H₁₁N₂)₂(C₁₁H₁₉O₂)]·CH₃CO₂C₂H₅, the Ir^III ion adopts a distorted octa-hedral coordination environment resulting from its coordination by two C,N-chelating 2,6-dimethyl-3-(pyridin-2-yl)pyridin-4-yl ligands and one O,O'-chelating 2,2,6,6-tetra-methylhepta-ne-3,5-dionate ligand. The C,N-chelating ligands are perpendicular to each other [dihedral angle between the least-squares planes = 87.86 (5)°] and are arranged in a cis-C,C' and trans-N,N' fashion. In the crystal, pairwise C-H⋯π inter-actions between inversion-related Ir^III compl

SUBMITTER: Park KM

PROVIDER: S-EPMC6127711 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature

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Crystal structure and luminescent properties of bis-[2,6-dimethyl-3-(pyridin-2-yl-κN)pyridin-4-yl-κC⁴](2,2,6,6-tetra-methylhepta-ne-3,5-dionato-κ²O,O')iridium(III) ethyl acetate monosolvate.

OmicsDI is part of the ELIXIR infrastructure

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Crystal structure and luminescent properties of bis-[2,6-dimethyl-3-(pyridin-2-yl-κN)pyridin-4-yl-κC4](2,2,6,6-tetra-methylhepta-ne-3,5-dionato-κ2O,O')iridium(III) ethyl acetate monosolvate.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Crystal structure and luminescent properties of bis-[2,6-dimethyl-3-(pyridin-2-yl-κN)pyridin-4-yl-κC⁴](2,2,6,6-tetra-methylhepta-ne-3,5-dionato-κ²O,O')iridium(III) ethyl acetate monosolvate.