Fluorination-Enhanced Ambient Stability and Electronic Tolerance of Black Phosphorus Quantum Dots.

ABSTRACT: The environmental instability and uneliminable electronic trap states in black phosphorus quantum dots (BPQDs) limit the optoelectronics and related applications of BPQDs. Here, fluorinated BPQDs (F-BPQDs) are successfully synthesized by using a facile electrochemical exfoliation and synchronous fluorination method. The F-BPQDs exhibit robust ambient stability and limited fluorination capability, showing a nonstoichiometric fluorination degree (D_F) maximum of ≈0.68. Density functional theory calculations confirm that due to the edge etching effect of fluorine adatoms, the simulated F-BPQDs become structurally unstable when D_F surpasses the limit. Furthermore, the trap states of BPQDs can be effectively eliminated via fluorination to obtain a coordination

SUBMITTER: Tang X 

PROVIDER: S-EPMC6145272 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature