Incorporating Methyl and Phenyl Substituted Stannylene Units into Oligosilanes. The Influence on Optical Absorption Properties.

ABSTRACT: Molecules containing catenated heavy group 14 atoms are known to exhibit the interesting property of σ-bond electron delocalization. While this is well studied for oligo- and polysilanes the current paper addresses the UV-absorption properties of small tin containing oligosilanes in order to evaluate the effects of Sn-Si and Sn-Sn bonds as well as the results of substituent exchange from methyl to phenyl groups. The new stannasilanes were compared to previously investigated oligosilanes of equal chain lengths and substituent pattern. Replacing the central SiMe₂ group in a pentasilane by a SnMe₂ unit caused a bathochromic shift of the low-energy band (λ_max = 260 nm) of 14 nm in the UV spectrum. If, instead of a SnMe_2, a SnPh₂ unit is incorporated, the bathochromic shif

SUBMITTER: Stella F 

PROVIDER: S-EPMC6149905 | biostudies-literature | 2017 Dec

REPOSITORIES: biostudies-literature