Dataset Information
Visible-Light Photocatalytic Difluoroalkylation-Induced 1, 2-Heteroarene Migration of Allylic Alcohols in Batch and Flow.
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ABSTRACT:
SUBMITTER: Wei XJ
PROVIDER: S-EPMC6154216 | biostudies-literature | 2018 Sep
REPOSITORIES: biostudies-literature
Publications
Visible-Light Photocatalytic Difluoroalkylation-Induced 1, 2-Heteroarene Migration of Allylic Alcohols in Batch and Flow.
The Journal of organic chemistry 20180727 18
A convenient method for the preparation of sp<sup>3</sup>-rich heterocycles is reported. The method comprises a photocatalytic difluoroalkylation-induced 1,2-heteroarene migration of allylic alcohols. Here we describe for the first time the benefits of using flow to facilitate such migration reactions, including shorter reaction times, higher selectivities, and opportunities to scale the chemistry. ...[more]