Cathodic Aromatic C,C Cross-Coupling Reaction via Single Electron Transfer Pathway.

ABSTRACT: We have successfully developed a novel cathodic cross-coupling reaction of aryl halides with arenes. Utilization of the cathodic single electron transfer (SET) mechanism for activation of aryl halides enables the cross-coupling reaction to proceed without the need for any transition metal catalysts or single electron donors in a mild condition. The SET from a cathode to an aryl halide initiates a radical chain by giving an anion radical of the aryl halide. The following propagation cycle also consists entirely of anion radical intermediates.

SUBMITTER: Qu Y 

PROVIDER: S-EPMC6155275 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature