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Four Pentasaccharide Resin Glycosides from Argyreia acuta.


ABSTRACT: Four pentasaccharide resin glycosides, acutacoside F-I (1-4), were isolated from the aerial parts of Argyreia acuta. These compounds were characterized as a group of macrolactones of operculinic acid A, and their lactonization site of 11S-hydroxyhexadecanoic acid was esterified at the second saccharide moiety (Rhamnose) at C-2. The absolute configuration of the aglycone was S. Their structures were elucidated by established spectroscopic and chemical methods.

SUBMITTER: Yu BW 

PROVIDER: S-EPMC6155385 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature

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Four Pentasaccharide Resin Glycosides from Argyreia acuta.

Yu Bang-Wei BW   Sun Jing-Jing JJ   Pan Jie-Tao JT   Wu Xiu-Hong XH   Yin Yong-Qin YQ   Yan You-Shao YS   Hu Jia-Yan JY  

Molecules (Basel, Switzerland) 20170311 3


Four pentasaccharide resin glycosides, acutacoside F-I (<b>1</b>-<b>4</b>), were isolated from the aerial parts of <i>Argyreia acuta</i>. These compounds were characterized as a group of macrolactones of operculinic acid A, and their lactonization site of 11<i>S</i>-hydroxyhexadecanoic acid was esterified at the second saccharide moiety (Rhamnose) at C-2. The absolute configuration of the aglycone was <i>S</i>. Their structures were elucidated by established spectroscopic and chemical methods. ...[more]

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