Electrostatic potential and valence modulation in La_0.7Sr_0.3MnO₃ thin films.

ABSTRACT: The Mn valence in thin film La_0.7Sr_0.3MnO₃ was studied as a function of film thickness in the range of 1-16 unit cells with a combination of non-destructive bulk and surface sensitive X-ray absorption spectroscopy techniques. Using a layer-by-layer valence model, it was found that while the bulk averaged valence hovers around its expected value of 3.3, a significant deviation occurs within several unit cells of the surface and interface. These results were supported by first principles calculations. The surface valence increases to up to Mn^3.7+, whereas the interface valence reduces down to Mn^2.5+. The change in valence from the expected bulk value is consistent with charge redistribution due to the polar discontinuity at the film-subs

SUBMITTER: Trappen R 

PROVIDER: S-EPMC6156561 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature