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Ultrasound-induced gelation of a giant macrocycle.

ABSTRACT: A 68-membered macrocycle undergoes ultrasound-induced supramolecular gelation in acetonitrile. The sonogel shows a remarkable thermostability, indicating that self-assembly is mediated by exceptionally robust non-covalent interactions. Model compounds indicate that the macrocyclic topology is essential for gelation to occur.

SUBMITTER: Nunez-Villanueva D 

PROVIDER: S-EPMC6156880 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature

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Ultrasound-induced gelation of a giant macrocycle.

Núñez-Villanueva Diego D   Jinks Michael A MA   Gómez Magenti Jorge J   Hunter Christopher A CA  

Chemical communications (Cambridge, England) 20180901 77

A 68-membered macrocycle undergoes ultrasound-induced supramolecular gelation in acetonitrile. The sonogel shows a remarkable thermostability, indicating that self-assembly is mediated by exceptionally robust non-covalent interactions. Model compounds indicate that the macrocyclic topology is essential for gelation to occur. ...[more]

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