High-yield scalable graphene nanosheet production from compressed graphite using electrochemical exfoliation.

ABSTRACT: Electrochemical exfoliation is a promising bulk method for producing graphene from graphite; in this method, an applied voltage drives ionic species to intercalate into graphite where they form gaseous species that expand and exfoliate individual graphene sheets. However, a number of obstacles have prevented this approach from becoming a feasible production route; the disintegration of the graphite electrode as the method progresses is the chief difficulty. Here we show that if graphite powders are contained and compressed within a permeable and expandable containment system, the graphite powders can be continuously intercalated, expanded, and exfoliated to produce graphene. Our data indicate both high yield (65%) and extraordinarily large lateral size (>30 μm) in the as-produced graphene.

SUBMITTER: Achee TC 

PROVIDER: S-EPMC6162260 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature