Rapid and Sensitive Determination of Vanillin Based on a Glassy Carbon Electrode Modified with Cu₂O-Electrochemically Reduced Graphene Oxide Nanocomposite Film.

ABSTRACT: A facile cuprous oxide nanoparticles functionalized electro-reduced graphene oxide modified glassy carbon electrode (denoted as Cu₂O NPs-ERGO/GCE) was fabricated via a simple physical adsorption and electrochemical reduction approach. Cyclic voltammetry and second-order derivative linear scan voltammetry were used to investigate the electrocatalysis oxidation of vanillin on the Cu₂O NPs-ERGO/GCE. The compound yielded a well-defined voltammetric response in 0.1 M H₂SO₄ at 0.916 V (vs. saturated calomel electrode (SCE)). A linear calibration graph was obtained in the concentration range of 0.1 μM to 10 μM and 10 μM to 100 μM, while the detection limit (S/N = 3) is 10 nM. In addition, the Cu₂O NPs-ERGO/GCE presented well anti-interference ability, stability, and reproducibility. It was used t

SUBMITTER: Ning J 

PROVIDER: S-EPMC6164793 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature