Boosting Lithium-Ion Storage Capability in CuO Nanosheets via Synergistic Engineering of Defects and Pores.

ABSTRACT: CuO is a promising anode material for lithium-ion batteries due to its high theoretical capacity, low cost, and non-toxicity. However, its practical application has been plagued by low conductivity and poor cyclability. Herein, we report the facile synthesis of porous defective CuO nanosheets by a simple wet-chemical route paired with controlled annealing. The sample obtained after mild heat treatment (300°C) exhibits an improved crystallinity with low dislocation density and preserved porous structure, manifesting superior Li-ion storage capability with high capacity (~500 mAh/g at 0.2 C), excellent rate (175 mAh/g at 2 C), and cyclability (258 mAh/g after 500 cycles at 0.5 C). The enhanced electrochemical performance can be ascribed to the synergy of porous nanosheet morphology and impro

SUBMITTER: Deng Z 

PROVIDER: S-EPMC6166579 | biostudies-literature | 2018

REPOSITORIES: biostudies-literature