The crystal structure of bis-{3,5-di-fluoro-2-[4-(2,4,6-tri-methyl-phen-yl)pyridin-2-yl]phen-yl}(picolinato)iridium(III) and its 4-tert-butyl-pyridin-2-yl analogue.

ABSTRACT: The crystal structures of bis-{3,5-di-fluoro-2-[4-(2,4,6-tri-methyl-phen-yl)pyridin-2-yl]phenyl-κ² N,C ¹}(picolinato-κ² N,O)iridium(III), [Ir(C₂₀H₁₆F₂N)₂(C₆H₄NO₂)], 1, and bis-[2-(4-tert-butyl-pyridin-2-yl)-3,5-di-fluoro-phenyl-κ² N,C ¹](picolinato-κ² N,O)iridium(III), [Ir(C₁₅H₁₄F₂N)₂(C₆H₄NO₂)], 2, are presented herein. These phospho-rescent cyclo-metallated iridium(III) compounds have been structurally investigated in order to better understand the nature of their blue-shifted emssions while maint

SUBMITTER: Sanner RD 

PROVIDER: S-EPMC6176426 | biostudies-literature | 2018 Oct

REPOSITORIES: biostudies-literature