Crystal structure of fac-{5-[(hexyl-aza-nium-yl)meth-yl]-2-(pyridin-2-yl)phenyl-κ² N,C ¹}bis-[2-(pyridin-2-yl)phenyl-κ² N,C ¹]iridium(III) chloride.

ABSTRACT: The asymmetric unit of the title compound, fac-[Ir(C₁₁H₈N)₂(C₁₈H₂₄N₂)]Cl or fac-[Ir(ppy)₂(Hppy-NC₆)]Cl, contains two [Ir(ppy)₂(ppy-NC₆)](H⁺) cations, two Cl^- anions and disordered solvent. In each complex mol-ecule, the Ir^III ion is coordinated by two C,N-bidentate 2-(pyridin-2-yl)phenyl ligands and one C,N-bidentate N-[4-(pyridin-2-yl)benz-yl]hexan-1-aminium ligand, leading to a distorted fac-octa-hedral coordination environment. In the crystal, the mol-ecules are linked by N-H⋯Cl, C-H⋯π and π-π inter-actions, forming a three-dimensional supra-molecular structure. The hexyl group of one mol-ec

SUBMITTER: Meksawangwong S 

PROVIDER: S-EPMC6176433 | biostudies-literature | 2018 Oct

REPOSITORIES: biostudies-literature