Self-organization into ferroelectric and antiferroelectric crystals via the interplay between particle shape and dipolar interaction.
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ABSTRACT: Ferroelectricity and antiferroelectricity are widely seen in various types of condensed matter and are of technological significance not only due to their electrical switchability but also due to intriguing cross-coupling effects such as electro-mechanical and electro-caloric effects. The control of the two types of dipolar order has practically been made by changing the ionic radius of a constituent atom or externally applying strain for inorganic crystals and by changing the shape of a molecule for organic crystals. However, the basic physical principle behind such controllability involving crystal-lattice organization is still unknown. On the basis of a physical picture that a competition of dipolar order with another type of order is essential to understand this phenomenon, here we dev
SUBMITTER: Takae K
PROVIDER: S-EPMC6176622 | biostudies-literature | 2018 Oct
REPOSITORIES: biostudies-literature
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