Unraveling the long-pursued Au₁₄₄ structure by x-ray crystallography.

ABSTRACT: The transition from nanocluster to nanocrystal is a central issue in nanoscience. The atomic structure determination of metal nanoparticles in the transition size range is challenging and particularly important in understanding the quantum size effect at the atomic level. On the basis of the rationale that the intra- and interparticle weak interactions play critical roles in growing high-quality single crystals of metal nanoparticles, we have reproducibly obtained ideal crystals of Au₁₄₄(SR)₆₀ and successfully solved its structure by x-ray crystallography (XRC); this structure was theoretically predicted a decade ago and has long been pursued experimentally but without success until now. Here, XRC reveals an interesting Au₁₂ hollow icosahedron in thiolated

SUBMITTER: Yan N 

PROVIDER: S-EPMC6184749 | biostudies-literature | 2018 Oct

REPOSITORIES: biostudies-literature