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Chromatography related performance of the Monitor for AeRosols and GAses in ambient air (MARGA): laboratory and field-based evaluation.


ABSTRACT: Evaluation of the semi-continuous Monitor for AeRosols and GAses in ambient air (MARGA, Metrohm Ap-plikon B.V.) was conducted with an emphasis on examination of accuracy and precision associated with processing of chromatograms. Using laboratory standards and atmospheric measurements, analytical accuracy, precision and method detection limits derived using the commercial MARGA software were compared to an alternative chromatography procedure consisting of a custom Java script to reformat raw MARGA conductivity data and Chromeleon (Thermo Scientific Dionex) software for peak integration. Our analysis revealed issues with accuracy and precision resulting from misidentification and misintegration of chromatograph peaks by the MARGA automated software as well as a systematic bias at low concen

SUBMITTER: Chen X 

PROVIDER: S-EPMC6192433 | biostudies-literature | 2017 Oct

REPOSITORIES: biostudies-literature