Pioneering Use of Ionic Liquid-Based Aqueous Biphasic Systems as Membrane-Free Batteries.

ABSTRACT: Aqueous biphasic systems (ABS) formed by water, ionic liquids (ILs), and salts, in which the two phases are water rich, are demonstrated here to act as potential membrane-free batteries. This concept is feasible due to the selective enrichment of redox organic molecules in each aqueous phase of ABS, which spontaneously form two liquid-phases above given concentrations of salt and IL. Therefore, the required separation of electrolytes in the battery is not driven by an expensive membrane that hampers mass transfer, but instead, by the intrinsic immiscibility of the two liquid phases. Moreover, the crosscontamination typically occurring through the ineffective membranes is determined by the partition coefficients of the active molecules between the two phases. The phase diagrams of a series

SUBMITTER: Navalpotro P 

PROVIDER: S-EPMC6193149 | biostudies-literature | 2018 Oct

REPOSITORIES: biostudies-literature