Biporous Metal-Organic Framework with Tunable CO₂/CH₄ Separation Performance Facilitated by Intrinsic Flexibility.

ABSTRACT: In this work, we report the synthesis of SION-8, a novel metal-organic framework (MOF) based on Ca(II) and a tetracarboxylate ligand TBAPy^4- endowed with two chemically distinct types of pores characterized by their hydrophobic and hydrophilic properties. By altering the activation conditions, we gained access to two bulk materials: the fully activated SION-8F and the partially activated SION-8P with exclusively the hydrophobic pores activated. SION-8P shows high affinity for both CO₂ ( Q_st = 28.4 kJ/mol) and CH₄ ( Q_st = 21.4 kJ/mol), while upon full activation, the difference in affinity for CO₂ ( Q_st = 23.4 kJ/mol) and CH₄ ( Q_st = 16.0 kJ/mol) is more pronounced. The intrinsic flexibility o

SUBMITTER: Gladysiak A 

PROVIDER: S-EPMC6202632 | biostudies-literature | 2018 Oct

REPOSITORIES: biostudies-literature