Tuning nuclear depolarization under MAS by electron T_1e.

ABSTRACT: The Cross-Effect (CE) Dynamic Nuclear Polarization (DNP) mechanism under Magic Angle Spinning (MAS) induces depletion or "depolarization" of the NMR signal, in the absence of microwave irradiation. In this study, the role of T_1e on nuclear depolarization under MAS was tested experimentally by systematically varying the local and global electron spin concentration using mono-, bi- and tri-radicals. These spin systems show different depolarization effects that systematically tracked with their different T_1e rates, consistent with theoretical predictions. In order to test whether the effect of T_1e is directly or indirectly convoluted with other spin parameters, the tri-radical system was doped with different concentrations of GdCl₃, only tuning the

SUBMITTER: Lund A 

PROVIDER: S-EPMC6208319 | biostudies-literature | 2018 Oct

REPOSITORIES: biostudies-literature