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Crystal structure of 5,15-dihexyl-5,15-di-hydro-benzo[2,1-b:4,3-c']dicarbazole hexane 0.375-solvate.

ABSTRACT: The title compound, C₃₈H₄₀N₂·0.375C₆H₁₄, crystallizes in the monoclinic space group P2₁/c and has a host-guest structure with the helicene molecules forming a porous structure and mol-ecules of hexane inserted into the holes. The dihedral angles between the two carbazole sections of the right- and left-handed helicenes are 27.44 (3) and 25.63 (3)°, respectively. There are no classical π-π inter-actions or hydrogen-bonding inter-actions present between adjacent mol-ecules in the crystal structure. The hexane solvent mol-ecule shows positional disorder.

SUBMITTER: Zhang D

PROVIDER: S-EPMC6218895 | biostudies-literature | 2018 Nov

REPOSITORIES: biostudies-literature

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Crystal structure of 5,15-dihexyl-5,15-di-hydro-benzo[2,1-b:4,3-c']dicarbazole hexane 0.375-solvate.

Zhang Dingchao D Shi Longqiang L Liu Zhi Z Li Li L Hu Zhenhao Z Cui Deliang D Yang Jing J

Acta crystallographica. Section E, Crystallographic communications 20181019 Pt 11

The title compound, C38H40N2·0.375C6H14, crystallizes in the monoclinic space group P21/c and has a host-guest structure with the helicene molecules forming a porous structure and mol-ecules of hexane inserted into the holes. The dihedral angles between the two carbazole sections of the right- and left-handed helicenes are 27.44 (3) and 25.63 (3)°, respectively. There are no classical π-π inter-actions or hydrogen-bo ...[more]

PMID: 30443390

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