Synthesis and structural characterization of four di-chlorido-bis-(cyclo-propyl-alkynyl-amidine)-metal complexes.

ABSTRACT: Deliberate hydrolysis of lithium cyclo-propyl-alkynylamidinates, Li[c-C₃H₅-C≡C(NR')₂] [R' = ⁱ Pr, Cy = cyclo-hex-yl)], afforded the hitherto unknown neutral cyclo-propyl-alkynyl-amidine derivatives c-C₃H₅-C≡C-C(NR')(NHR') [R' = ⁱ Pr (1), Cy (2)]. Subsequent reactions of 1 or 2 with metal(II) chlorides, MCl₂ (M = Mn, Fe, Co), provided the title complexes di-chlorido-bis-(3-cyclo-propyl-N,N'-diisopropyl-prop-2-ynamidine)-manganese(II), [MnCl₂(C₁₂H₂₀N₂)₂], (3), di-chlorido-bis-(3-cyclo-propyl-N,N'-diisopropyl-prop-

SUBMITTER: Wang S 

PROVIDER: S-EPMC6218897 | biostudies-literature | 2018 Nov

REPOSITORIES: biostudies-literature