Crystal structure of di-chlorido-bis-{μ-2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}{2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}cadmium(II)cobalt(III) monohydrate.

ABSTRACT: The title compound, [CoCd(C₉H₁₀NO₂)₃Cl₂]·H₂O, is a solvatomorph of the corresponding hemihydrate recently published by us [Nesterova et al. (2018 ▸). Appl. Cat. A, 560, 171-184]. The current structure reveals different cell parameters and space group compared with the published one while both are monoclinic with almost the same cell volume. The title compound is formed of discrete neutral dinuclear mol-ecules with no crystallographically imposed symmetry and water mol-ecules of crystallization. The overall geometry about the cobalt(III) ion is octa-hedral with an N₃O₃ environment; each ligand acts as a meridional ONO donor. The Cd^II coordination sphere approximates an irr

SUBMITTER: Vassilyeva OY 

PROVIDER: S-EPMC6218914 | biostudies-literature | 2018 Nov

REPOSITORIES: biostudies-literature