Electronic chirality inversion of lanthanide complex induced by achiral molecules.

ABSTRACT: A novel mechanism for chiroptical activity inversion based on the electronic structure of metal complexes without Λ- or Δ-type structure change was demonstrated spectroscopically and theoretically. To demonstrate the mechanism, a europium (Eu(III)) complex with chiral (+)-3-(trifluoroacetyl)camphor (+tfc) and achiral triphenylphosphine oxide (tppo) was prepared. The steric and electronic structures of the Eu(III) complex were adjusted by additional achiral tppo and coordinating acetone molecules, and were characterised by ¹H NMR, photoluminescence, and emission lifetime measurements. The optical activity of the Eu(III) complex in solution was evaluated by circularly polarized luminescence (CPL) measurements. CPL sign inversion, which was independent of Λ- or Δ-type structure cha

SUBMITTER: Wada S 

PROVIDER: S-EPMC6219555 | biostudies-literature | 2018 Nov

REPOSITORIES: biostudies-literature