Immobilizing Polyether Imidazole Ionic Liquids on ZSM-5 Zeolite for the Catalytic Synthesis of Propylene Carbonate from Carbon Dioxide.

ABSTRACT: Traditional ionic liquids (ILs) catalysts suffer from the difficulty of product purification and can only be used in homogeneous catalytic systems. In this work, by reacting ILs with co-catalyst (ZnBr₂), we successfully converted three polyether imidazole ionic liquids (PIILs), i.e., HO-[Poly-epichlorohydrin-methimidazole]Cl (HO-[PECH-MIM]Cl), HOOC-[Poly-epichlorohydrin-methimidazole]Cl (HOOC-[PECH-MIM]Cl), and H₂N-[Poly-epichlorohydrin-methimidazole]Cl (H₂N-[PECH-MIM]Cl), to three composite PIIL materials, which were further immobilized on ZSM-5 zeolite by chemical bonding to result in three immobilized catalysts, namely ZSM-5-HO-[PECH-MIM]Cl/[ZnBr₂], ZSM-5-HOOC-[PECH-MIM]Cl/[ZnBr₂], and ZSM-5-H₂N-[PECH-MIM]Cl/[ZnBr₂]. Their structures, thermal stabilities, and morphologies were fully cha

SUBMITTER: Guo L 

PROVIDER: S-EPMC6222835 | biostudies-literature | 2018 Oct

REPOSITORIES: biostudies-literature