Phase transition and switchable dielectric behaviours in an organic-inorganic hybrid compound: (3-nitroanilinium)2(18-crown-6)2(H2PO4)2(H3PO4)3(H2O).
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ABSTRACT: An organic-inorganic hybrid compound with an extensive three-dimensional (3D) crystal structure, (3-nitroanilinium)2(18-crown-6)2(H2PO4)2(H3PO4)3(H2O) (1), was synthesized under slow evaporation conditions. Differential scanning calorimetry measurements indicated that 1 underwent a reversible phase transition at ca 231 K with a hysteresis width of 10 K. Variable-temperature X-ray single-crystal diffraction revealed that the phase transition of 1 can be ascribed to coupling of pendulum-like motions of its nitro group with proton transfer in O-H···O hydrogen bonds of the 3D framework. The temperature dependence of its dielectric permittivity demonstrated a step-like
SUBMITTER: Liu Y
PROVIDER: S-EPMC6227991 | biostudies-literature | 2018 Oct
REPOSITORIES: biostudies-literature
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