Amorphous Vanadium Oxide Thin Films as Stable Performing Cathodes of Lithium and Sodium-Ion Batteries.

ABSTRACT: Herein, we report additive- and binder-free pristine amorphous vanadium oxide (a-VOx) for Li- and Na-ion battery application. Thin films of a-VOx with a thickness of about 650 nm are grown onto stainless steel substrate from crystalline V₂O₅ target using pulsed laser deposition (PLD) technique. Under varying oxygen partial pressure (pO₂) environment of 0, 6, 13 and 30 Pa, films bear O/V atomic ratios 0.76, 2.13, 2.25 and 2.0, respectively. The films deposited at 6‑30 Pa have a more atomic percentage of V⁵⁺ than that of V⁴⁺ with a tendency of later state increased as pO₂ rises. Amorphous VOx films obtained at moderate pO₂ levels are found superior to other counterparts for cathode application in Li- and Na-ion batt

SUBMITTER: Petnikota S 

PROVIDER: S-EPMC6235769 | biostudies-literature | 2018 Nov

REPOSITORIES: biostudies-literature