Phase-Selective Synthesis of CIGS Nanoparticles with Metastable Phases Through Tuning Solvent Composition.

ABSTRACT: I-III-VI₂ compounds have shown great interests in the application of functional semiconductors. Among them, Cu(In,Ga)S₂ has been a promising candidate due to its excellent optoelectronic properties. Although the polymorphs of Cu(In,Ga)S₂ have been attracted extensive attentions, the efforts to developing the methodologies for phase-controlled synthesis of them are rare. In this paper, we reported a phase-selective synthesis of CIGS nanoparticles with metastable phases via simply changing the composition of solvents. For the wet chemistry synthesis, the microstructure of the initial nuclei is decisive to the crystal structure of final products. In the formation of Cu(In,Ga)S₂, the solvent environment is the key factor, which could affect the coord

SUBMITTER: Zhang X 

PROVIDER: S-EPMC6235770 | biostudies-literature | 2018 Nov

REPOSITORIES: biostudies-literature