Push-Pull Zinc Porphyrins as Light-Harvesters for Efficient Dye-Sensitized Solar Cells.

ABSTRACT: Dye-sensitized solar cell (DSSC) has been attractive to scientific community due to its eco-friendliness, ease of fabrication, and vivid colorful property etc. Among various kinds of sensitizers, such as metal-free organic molecules, metal-complex, natural dyes etc., porphyrin is one of the most promising sensitizers for DSSC. The first application of porphyrin for sensitization of nanocrystaline TiO₂ can be traced back to 1993 by using [tetrakis(4-carboxyphenyl) porphyrinato] zinc(II) with an overall conversion efficiency of 2.6%. After 10 years efforts, Officer and Grätzel improved this value to 7.1%. Later in 2009, by constructing porphyrin sensitizer with an arylamine as donor and a benzoic acid as acceptor, Diau and Yeh demonstrated that this donor-acceptor fr

SUBMITTER: Lu J 

PROVIDER: S-EPMC6251255 | biostudies-literature | 2018

REPOSITORIES: biostudies-literature