Dataset Information

Titanium Imido Complexes via Displacement of -SiMe₃ and C-H Bond Activation in a Ti(III) Amido Complex, Promoted by a Cyclic (Alkyl)(Amino) Carbene (cAAC).

ABSTRACT: A strong σ-donating cyclic (alkyl)(amino) carbene (cAAC) triggers rearrangement of the silyl(aryl) amido ligand -N(SiMe₃)Dipp (Dipp = 2,6-diisopropylphenyl) in the coordination sphere of titanium(III) to afford a novel zwitterionic titanium imido complex with a TiCH₂SiMe₂[cAAC] linkage. Reduction of this species produces a new DippN=Ti imido complex containing a cAAC-centered radical species, characterized by single crystal diffraction analysis and electron paramagnetic resonance spectroscopy.

SUBMITTER: Ye Q

PROVIDER: S-EPMC6261457 | biostudies-literature | 2017 May

REPOSITORIES: biostudies-literature

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Dataset Information

Titanium Imido Complexes via Displacement of -SiMe₃ and C-H Bond Activation in a Ti(III) Amido Complex, Promoted by a Cyclic (Alkyl)(Amino) Carbene (cAAC).

OmicsDI is part of the ELIXIR infrastructure

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Dataset Information

Titanium Imido Complexes via Displacement of -SiMe3 and C-H Bond Activation in a Ti(III) Amido Complex, Promoted by a Cyclic (Alkyl)(Amino) Carbene (cAAC).

OmicsDI is part of the ELIXIR infrastructure

Tweets

Titanium Imido Complexes via Displacement of -SiMe₃ and C-H Bond Activation in a Ti(III) Amido Complex, Promoted by a Cyclic (Alkyl)(Amino) Carbene (cAAC).