Alternating Ring-Opening Metathesis Polymerization (AROMP) of Hydrophobic and Hydrophilic Monomers Provides Oligomers with Side-Chain Sequence Control.

ABSTRACT: We report the formation of oligomers with side-chain sequence control using ruthenium-catalyzed alternating ring-opening metathesis polymerization (AROMP). These oligomers are prepared through sequential, stoichiometric addition of bicyclo[4.2.0]oct-1(8)-ene-8-carboxamide (monomer A) at 85 °C and cyclohexene (monomer B) at 45 °C to generate sequences up to 24 monomeric units composed of (A-alt- B) _n and (A'-alt-B) _n microblocks, where n ranges from 1 to 6. Herein, monomer A has an alkyl side chain, and monomer A' has a glycine methyl ester side chain. Increasing microblock size from one to six results in an increasing water contact angle on spin-coated thin films, despite the constant ratio o

SUBMITTER: Li G 

PROVIDER: S-EPMC6262599 | biostudies-literature | 2018 Jun

REPOSITORIES: biostudies-literature