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Oxidatively Locked [Co₂L₃]⁶⁺ Cylinders Derived from Bis(bidentate) 2-Pyridyl-1,2,3-triazole "Click" Ligands: Synthesis, Stability, and Antimicrobial Studies.

ABSTRACT: A small family of [Co₂(L_pytrz)₃]⁶⁺ cylinders was synthesised from bis(bidentate) 2-pyridyl-1,2,3-triazole "click" ligands (L_pytrz) through an "assembly-followed-by-oxidation" method. The cylinders were characterised using ¹H, ¹³C, and DOSY NMR, IR, and UV-Vis spectroscopies, along with electrospray ionisation mass spectrometry (ESMS). Stability studies were conducted in dimethyl sulfoxide (DMSO) and D₂O. In contrast to similar, previously studied, [Fe₂(L_pytrz)₃]⁴⁺ helicates the more kinetically inert [Co₂(L_pytrz)₃]⁶⁺ systems proved stable (over a period of days) when exposed to DMSO and were even more stable in D₂O. The triply stranded [Co₂(L_pytrz)₃]^6+<

SUBMITTER: Vasdev RA

PROVIDER: S-EPMC6273053 | biostudies-literature | 2016 Nov

REPOSITORIES: biostudies-literature

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Dataset Information

Oxidatively Locked [Co₂L₃]⁶⁺ Cylinders Derived from Bis(bidentate) 2-Pyridyl-1,2,3-triazole "Click" Ligands: Synthesis, Stability, and Antimicrobial Studies.

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Dataset Information

Oxidatively Locked [Co₂L₃]6+ Cylinders Derived from Bis(bidentate) 2-Pyridyl-1,2,3-triazole "Click" Ligands: Synthesis, Stability, and Antimicrobial Studies.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Oxidatively Locked [Co₂L₃]⁶⁺ Cylinders Derived from Bis(bidentate) 2-Pyridyl-1,2,3-triazole "Click" Ligands: Synthesis, Stability, and Antimicrobial Studies.