Isolation of a Cyclic (Alkyl)(amino)germylene.

ABSTRACT: A 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC₃N five-membered ring skeleton. By reducing 2 with KC₈, cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with TEMPO, N₂O and S₈, producing the 1:2 adduct 4, the oxo-bridged dimer 5 and the sulfido-bridged dimer 6, respectively.

SUBMITTER: Wang L 

PROVIDER: S-EPMC6273211 | biostudies-literature | 2016 Jul

REPOSITORIES: biostudies-literature