Quantitative constraints on autoxidation and dimer formation from direct probing of monoterpene-derived peroxy radical chemistry.

ABSTRACT: Organic peroxy radicals (RO₂) are key intermediates in the atmospheric degradation of organic matter and fuel combustion, but to date, few direct studies of specific RO₂ in complex reaction systems exist, leading to large gaps in our understanding of their fate. We show, using direct, speciated measurements of a suite of RO₂ and gas-phase dimers from O₃-initiated oxidation of α-pinene, that ∼150 gaseous dimers (C_16-20H_24-34O_4-13) are primarily formed through RO₂ cross-reactions, with a typical rate constant of 0.75-2 × 10^-12 cm³ molecule^-1 s^-1 and a lower-limit dimer formation branching ratio of 4%. These findings imply a gaseous dimer yield that varies strong

SUBMITTER: Zhao Y 

PROVIDER: S-EPMC6275546 | biostudies-literature | 2018 Nov

REPOSITORIES: biostudies-literature