Single-Electron Redox Chemistry on the [Cp*Rh] Platform Enabled by a Nitrated Bipyridyl Ligand.

ABSTRACT: [Cp*Rh] complexes (Cp* = pentamethylcyclopentadienyl) are attracting renewed interest in coordination chemistry and catalysis, but these useful compounds often undergo net two-electron redox cycling that precludes observation of individual one-electron reduction events. Here, we show that a [Cp*Rh] complex bearing the 4,4'-dinitro-2,2'-bipyridyl ligand (dnbpy) (3) can access a distinctive manifold of five oxidation states in organic electrolytes, contrasting with prior work that found no accessible reductions in aqueous electrolyte. These states are readily generated from a newly isolated and fully characterized rhodium(III) precursor complex 3, formulated as [Cp*Rh(dnbpy)Cl]PF₆. Single-crystal X-ray diffraction (XRD) data, previously unavailable for the dnbpy ligand bound to

SUBMITTER: Moore WNG 

PROVIDER: S-EPMC6278249 | biostudies-literature | 2018 Nov

REPOSITORIES: biostudies-literature