Gas Phase Hydrogenation of Furaldehydes via Coupling with Alcohol Dehydrogenation over Ceria Supported Au-Cu.

ABSTRACT: We have investigated the synthesis and application of Au-Cu/CeO₂ (Cu: Au = 2) in the continuous gas phase (P = 1 atm; T = 498 K) coupled hydrogenation of 5-hydroxymethyl-2-furaldehyde (HMF) with 2-butanol dehydrogenation. STEM-EDX analysis revealed a close surface proximity of both metals in Au-Cu/CeO₂ post-TPR. XPS measurements suggest (support → metal) charge transfer to form Auδ- and strong metal-support interactions to generate Cu⁰ and Cu⁺. Au-Cu/CeO₂ promoted the sole formation of 2,5-dihydroxymethylfuran (DHMF) and 2-butanone in the HMF/2-butanol coupling with full hydrogen utilisation. Under the same reaction conditions, Au/CeO₂ was fully selective to DHMF in standard HMF hydrogenation (using an external hydrogen supply), but delivered a lower production rate and utilised less than

SUBMITTER: Pischetola C 

PROVIDER: S-EPMC6278317 | biostudies-literature | 2018 Nov

REPOSITORIES: biostudies-literature