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Olefin metathesis catalysts embedded in ?-barrel proteins: creating artificial metalloproteins for olefin metathesis.

ABSTRACT: This review summarizes the recent progress of Grubbs-Hoveyda (GH) type olefin metathesis catalysts incorporated into the robust fold of ?-barrel proteins. Anchoring strategies are discussed and challenges and opportunities in this emerging field are shown from simple small-molecule transformations over ring-opening metathesis polymerizations to in vivo olefin metathesis.

SUBMITTER: Sauer DF 

PROVIDER: S-EPMC6278764 | biostudies-literature | 2018

REPOSITORIES: biostudies-literature

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Olefin metathesis catalysts embedded in β-barrel proteins: creating artificial metalloproteins for olefin metathesis.

Sauer Daniel F DF   Schiffels Johannes J   Hayashi Takashi T   Schwaneberg Ulrich U   Okuda Jun J  

Beilstein journal of organic chemistry 20181119

This review summarizes the recent progress of Grubbs-Hoveyda (GH) type olefin metathesis catalysts incorporated into the robust fold of β-barrel proteins. Anchoring strategies are discussed and challenges and opportunities in this emerging field are shown from simple small-molecule transformations over ring-opening metathesis polymerizations to in vivo olefin metathesis. ...[more]

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