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Crystal structure of bis-(μ₂-meth-anolato-κO:κO)hexa-methyl-bis-(μ₂-tri-phenyl-acetato-κO:κO')bis-(μ₂-tri-phenyl-acetato-κ² O,O':κO)dialuminiumdi-lanthanum toluene tetra-solvate.

ABSTRACT: The title compound, [Al₂La₂(C₂₀H₁₅O₂)₄(CH₃)₆(CH₃O)₂]·4CH₃C₆H₅ or [{La(Ph₃CCOO)₂(Me₃AlOMe)}₂]·4CH₃C₆H₅, was formed in a reaction between lanthanum tris-(tetra-methyl-aluminate) and tri-phenyl-acetic acid (1:1) with unintended partial oxidation. The tri-phenyl-acetate ligand exhibits μ₂-κ¹ O:κ¹ O' bridging and μ₂-κ² O,O':κ¹ O semi-bridging coordination modes, forming a dimeric La₂(μ-OCO)₄ core. The semi-bridging tri-phenyl-acetate group provides additiona

SUBMITTER: Vinogradov AA

PROVIDER: S-EPMC6281095 | biostudies-literature | 2018 Dec

REPOSITORIES: biostudies-literature

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Crystal structure of bis-(μ₂-meth-anolato-κO:κO)hexa-methyl-bis-(μ₂-tri-phenyl-acetato-κO:κO')bis-(μ₂-tri-phenyl-acetato-κ² O,O':κO)dialuminiumdi-lanthanum toluene tetra-solvate.

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Crystal structure of bis-(μ2-meth-anolato-κO:κO)hexa-methyl-bis-(μ2-tri-phenyl-acetato-κO:κO')bis-(μ2-tri-phenyl-acetato-κ2 O,O':κO)dialuminiumdi-lanthanum toluene tetra-solvate.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Crystal structure of bis-(μ₂-meth-anolato-κO:κO)hexa-methyl-bis-(μ₂-tri-phenyl-acetato-κO:κO')bis-(μ₂-tri-phenyl-acetato-κ² O,O':κO)dialuminiumdi-lanthanum toluene tetra-solvate.