Three-dimensional atomic scale electron density reconstruction of octahedral tilt epitaxy in functional perovskites.

ABSTRACT: Octahedral tilts are the most ubiquitous distortions in perovskite-related structures that can dramatically influence ferroelectric, magnetic, and electronic properties; yet the paradigm of tilt epitaxy in thin films is barely explored. Non-destructively characterizing such epitaxy in three-dimensions for low symmetry complex tilt systems composed of light anions is a formidable challenge. Here we demonstrate that the interfacial tilt epitaxy can transform ultrathin calcium titanate, a non-polar earth-abundant mineral, into high-temperature polar oxides that last above 900 K. The comprehensive picture of octahedral tilts and polar distortions is revealed by reconstructing the three-dimensional electron density maps across film-substrate interfaces with atomic resolution using coherent Brag

SUBMITTER: Yuan Y 

PROVIDER: S-EPMC6283878 | biostudies-literature | 2018 Dec

REPOSITORIES: biostudies-literature