Highly efficient room-temperature phosphorescence and afterglow luminescence from common organic fluorophores in 2D hybrid perovskites.

ABSTRACT: Regardless of rapid development of organic room-temperature phosphorescence (RTP) originating from phosphors in crystals, highly efficient and persistent RTP from common fluorophores is very rare. Herein, 1,8-naphthalimide (NI), a common organic fluorophore, is doped into organic cations of 2D layered organic/inorganic hybrid perovskites (OIHPs) to yield thin films and powders with yellow RTP of NI in air. The triplet excitons of NI are mainly derived from Wannier excitons of inorganic perovskite through energy transfer (ET) for films, and from singlet excitons of NI through intersystem crossing (ISC) for powder. Consequently, the quantum yield (Φ _P), lifetime (τ) and color of RTP can be tuned by changing the fluorophore and halide in the perovskites, as well as th

SUBMITTER: Yang S 

PROVIDER: S-EPMC6296360 | biostudies-literature | 2018 Dec

REPOSITORIES: biostudies-literature