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Thickness-Dependent Swelling Behavior of Vapor-Deposited Smart Polymer Thin Films.


ABSTRACT: In this contribution, the temperature-dependent swelling behavior of vapor-deposited smart polymer thin films is shown to depend on cross-linking and deposited film thickness. Smart polymers find application in sensor and actuator setups and are mostly fabricated on delicate substrates with complex nanostructures that need to be conformally coated. As initiated chemical vapor deposition (iCVD) meets these specific requirements, the present work concentrates on temperature-dependent swelling behavior of iCVD poly(N-isopropylacrylamide) thin films. The transition between swollen and shrunken state and the corresponding lower critical solution temperature (LCST) was investigated by spectroscopic ellipsometry in water. The films' density in the dry state evaluated from X-ray reflectivit

SUBMITTER: Muralter F 

PROVIDER: S-EPMC6300310 | biostudies-literature | 2018 Dec

REPOSITORIES: biostudies-literature