Ultrathin Nanosheet of Graphdiyne-Supported Palladium Atom Catalyst for Efficient Hydrogen Production.

ABSTRACT: Atomic catalysts are promising alternatives to bulk catalysts for the hydrogen evolution reaction (HER), because of their high atomic efficiencies, catalytic activities, and selectivities. Here, we report the ultrathin nanosheet of graphdiyne (GDY)-supported zero-valent palladium atoms and its direct application as a three-dimensional flexible hydrogen-evolving cathode. Our theoretical and experimental findings verified the successful anchoring of Pd⁰ to GDY and the excellent catalytic performance of Pd⁰/GDY. At a very low mass loading (0.2%: 1/100 of the 20 wt % Pt/C), Pd⁰/GDY required only 55 mV to reach 10 mA cm^-2 (smaller than 20 wt % Pt/C); it showed larger mass activity (61.5 A mg_metal^-1) and turnover frequency (16.7 s

SUBMITTER: Yu H 

PROVIDER: S-EPMC6305764 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature