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Carbohydrate/DBU Cocatalyzed Alkene Diboration: Mechanistic Insight Provides Enhanced Catalytic Efficiency and Substrate Scope.

ABSTRACT: A mechanistic investigation of the carbohydrate/DBU cocatalyzed enantioselective diboration of alkenes is presented. These studies provide an understanding of the origin of stereoselectivity and also reveal a strategy for enhancing reactivity and broadening the substrate scope.

SUBMITTER: Yan L 

PROVIDER: S-EPMC6313253 | biostudies-literature | 2018 Mar

REPOSITORIES: biostudies-literature

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Carbohydrate/DBU Cocatalyzed Alkene Diboration: Mechanistic Insight Provides Enhanced Catalytic Efficiency and Substrate Scope.

Yan Lu L   Meng Yan Y   Haeffner Fredrik F   Leon Robert M RM   Crockett Michael P MP   Morken James P JP  

Journal of the American Chemical Society 20180302 10

A mechanistic investigation of the carbohydrate/DBU cocatalyzed enantioselective diboration of alkenes is presented. These studies provide an understanding of the origin of stereoselectivity and also reveal a strategy for enhancing reactivity and broadening the substrate scope. ...[more]

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